Conversion of jet biofuel range hydrocarbons from palm oil over zeolite hybrid catalyst

نویسندگان

چکیده

The catalytic conversion of palm oil was carried out over four zeolite catalysts—Y, ZSM-5, Y-ZSM-5 hybrid, and Y/ZSM-5 composite—to produce jet biofuel with high amount alkanes low aromatic hydrocarbons. hybrid catalyst synthesized using crystalline Y as the seed for growth ZSM-5. Synthesized catalysts were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, field-emission scanning electron microscopy, temperature programmed desorption ammonia, while chemical compositions analyzed gas chromatography-mass spectrometry (GC-MS). resulted in highest yield (42 wt%) biofuel: a selectivity range (51%) hydrocarbons (25%). Zeolite produced decreased percentage alkane (30%) significant increase (57%). to hydrocarbon compounds achieved (99%), followed composite (96%), (91%), ZSM-5 (74%). reaction routes converting involve deoxygenation fatty acids into C15–C18 via decarboxylation decarbonylation, cracking C8–C14 alkanes, cycloalkanes well aromatization hydrocarbon.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Catalytic conversion of isophorone to jet-fuel range aromatic hydrocarbons over a MoO(x)/SiO2 catalyst.

For the first time, jet fuel range C8-C9 aromatic hydrocarbons were synthesized in high carbon yield (∼80%) by the catalytic conversion of isophorone over MoO(x)/SiO2 at atmospheric pressure. A possible reaction pathway was proposed according to the control experiments and the intermediates generated during the reaction.

متن کامل

Jet-Fuel Range Hydrocarbons from Biomass-Derived Sorbitol over Ni-HZSM-5/SBA-15 Catalyst

Aromatics and cyclic-hydrocarbons are the significant components of jet fuel with high energy-density. However, conventional technologies for bio-fuel production cannot produce these products without further aromatization and isomerization. In this work, renewable liquid fuel with high content of aromatics and cyclic-hydrocarbons was obtained through aqueous catalytic conversion of biomass sorb...

متن کامل

Conversion of Methanol to Hydrocarbons over Ni-zsm-5 Catalyst

As stock of crude oil is limited, new resources for fuel and petrochemicals are required to be developed. Natural gas or biogas can be easily converted into methanol which can be converted into gasoline and olefins. This study uses zeolite catalyst (ZSM-5) and its modification by Ni to convert methanol to hydrocarbons (MTH). Catalysts are studied at different temperatures and at different loadi...

متن کامل

Aromatic Hydrocarbons Production from Catalysis of Douglas Fir Sawdust Pellets Pyrolysis Vapor over Zeolite Catalyst

The direct catalytic cracking of biomass pyrolysis vapor into aromatics derived from Douglas fir sawdust pellets was tested using an upfront microwave pyrolysis process coupled with a packed-bed catalysis process using a ZSM-5 Zeolite catalyst. A central composite experimental design (CCD) was used to optimize the bio-oil and syngas yields. The effects of temperature and inverse weight hourly s...

متن کامل

Nano Catalyst for CO2 Conversion to Hydrocarbons

A supported trimetallic nano catalyst and a fixed bed catalytic process have been developed for the conversion of CO2 + H2O (in the form of steam) + 1% H2 to alcohol and propyne The mixture of CO2 +H2O and H2 is passed over Ru:Mn:Ni nano catalyst dispersed on a high surface area antase titanium dioxide catalyst support at 773 K and at atmospheric pressure with the gas space velocity of 6000-700...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Nanomaterials and Nanotechnology

سال: 2021

ISSN: ['1847-9804']

DOI: https://doi.org/10.1177/1847980420981536